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Tert-Butyl Peroxybenzoate 80% Solution with Acetyl Acetone - China Suppliers and Factory for Polymerization and Crosslinking

TBPB is a highly efficient initiator manufactured in China, specifically designed for the polymerization of ethylene under high-pressure conditions, applicable in both autoclave and tubular processes. This product is also ideal for the crosslinking of EPDM rubber compounds at ambient temperatures, achieving results within a few weeks. As a leading supplier in the industry, our factory ensures the highest quality of TBPB, making it an essential choice for your polymerization and crosslinking needs

    Half Life Data
    TBPB 80% products
    TBPB 80% Specifications
    Molecular formula C11H14O3
    Molecular weight 194.23
    CAS NO. 614-45-9
    UN NO. 3103
    EINECS 210-382-2
    Chemical name Tert-Butyl peroxybenzoate 80%
    Specification
    Property Value / Limit
    Appearance clear liquid
    Assay 78% min.
    Color 50 Pt-Co max
    tert-Butyl hydroperoxide 1000 mg/kg max
    Inorganic + organic hydrolyzable chloride 50 mg/kg max.
    Package and Storage

    Standard packaging size for TBPB is 25 kg net or 180kg net. Smaller packaging size is available on request.

    Applications
    Styrene polymerization

    TBPB may be utilized for the polymerization and copolymerization of styrene within the 100-140℃ temperature range. The temperature is gradually raised during the polymerization process.

    Acrylates and methacrylates polymerization

    TBPB can serve as an initiator for the solution (co)polymerization of acrylates and methacrylates at temperatures ranging from 100 to 170℃, particularly for coatings. It can also be used as an initiator for the bulk and suspension (co)polymerization of acrylates and methacrylates.

    Ethylene polymerization

    TBPB is an effective initiator for the polymerization of ethylene under high pressure in both autoclave and tubular processes. Combinations with other peroxides are employed to achieve a wide range of polymerization temperatures. TBPB exhibits activity within the 220-270℃ temperature range, depending on the reaction conditions.

    Other uses

    TBPB can also be employed for the (co)polymerization of acrylonitrile and vinyl acetate.

    Crosslinking peroxides

    TBPB is suitable for crosslinking EPDM rubber compounds at ambient temperature over several weeks. Rubber compounds containing TBPB offer a balance between processing safety and rapid curing.

    Peroxides for thermoset resins

    Tert-butyl peroxybenzoate, an aromatic perester, is utilized for curing unsaturated polyester resins at elevated temperatures. TBPB is the preferred curing agent for UP resin-based Hot Press Moulding formulations (SMC, BMC, ZMC, etc.) within the 120-170℃ temperature range.

    Frequently Asked Questions (FAQ)
    1. What is the molecular formula and CAS number of TBPB 80%?
    The molecular formula of TBPB (Tert-Butyl peroxybenzoate 80%) is C11H14O3 and its CAS registry number is 614-45-9.
    2. What are the standard packaging options for TBPB?
    The standard packaging sizes for TBPB are 25 kg net or 180 kg net. Smaller custom packaging sizes can also be provided upon request.
    3. At what temperatures is TBPB used for styrene polymerization?
    TBPB is typically used for the polymerization and copolymerization of styrene within the temperature range of 100-140℃, with temperatures raised gradually during the process.
    4. Can TBPB be used for crosslinking EPDM rubber?
    Yes, TBPB is highly suitable for crosslinking EPDM rubber compounds at ambient temperatures over a period of several weeks, offering a good balance between processing safety and fast curing.
    5. What is the role of TBPB in thermoset resins?
    TBPB is an aromatic perester preferred for curing unsaturated polyester (UP) resin-based Hot Press Moulding formulations (such as SMC, BMC, and ZMC) within a temperature range of 120-170℃.
    6. What are the key chemical purity specifications of TBPB?
    TBPB has a minimum assay of 78%, a maximum color level of 50 Pt-Co, a maximum of 1000 mg/kg of tert-butyl hydroperoxide, and a maximum of 50 mg/kg of inorganic + organic hydrolyzable chloride.

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