Badeecadaha

Budada BPO 50% waa budo yar oo aan lahayn wax lagu shiido oo ka kooban 50% dibenzoyl peroxide, plasticizer pathalate ester ah oo lagu cabiray silica, kaas oo si fudud oo dhakhso ah loogu kala firdhin karo oo lagu milmi karo polyester aan dheregsanayn iyo resins acrylic ah. Xitaa heerkul aad u hooseeya daawo wanaagsan ayaa la heli karaa. Ku milmi kara khamriga, esters-ka, ether-ka, olefins-ka iyo dareerayaasha dabiiciga ah. Kuma milmi karo biyaha.

BPO 50% koollada waa kala firdhis fiican oo dibenzoyl peroxide ah oo ku jira qaab koollo kareem ah oo aan kala go 'lahayn oo dabka u adkaysta, kaas oo si fudud loogu milmi karo resins iyo monomers.

Badeecadani waa mid aan khatar badan lahayn oo ka fudud in la isticmaalo marka loo eego noocyada farsamada ama qalalan ee dibenzoyl peroxide. Si yar ayuu ugu milmaa aalkolada, dareerayaasha batroolka, kuma milmi karo dareerayaasha koloriin ku jira.

Waxaa badanaa loo isticmaalaa sidii bilow xagjir ah oo ku saabsan polymerization-ka iyo copolymerization-ka monomers-ka kala duwan, oo ay ku jiraan styrene, heerkul gaar ah, badanaa inta u dhaxaysa 95-125°C. Inta lagu jiro habka polymerization-ka, heerkulka badanaa waxaa lagu kordhiyaa tallaabooyin si loo fududeeyo falcelinta.
Isku-dhafkan waxaa loo yaqaanaa awooddiisa uu ku bilaabo fal-celinta isku-xidhka iyo polymerization-ka, taasoo ka dhigaysa qayb muhiim ah oo ka mid ah soo saarista polymers-ka, balaastikada, dhejisyada, dahaarka, iyo alaabada kale ee ku salaysan polymer-ka.
Tert-Butylperoxy isopropyl carbonate waxaa loo isticmaalaa soo saarista resins-ka thermoset, kuwaas oo si weyn loogu isticmaalo warshadaha sida dhismaha, baabuurta, iyo hawada sare sababtoo ah iska caabbinta kulaylka iyo cimri dhererka.
Waa muhiim in la maareeyo oo la keydiyo Tert-Butylperoxy isopropyl carbonate iyadoo la adeegsanayo tallaabooyin badbaado oo habboon, maadaama ay tahay walax falgal ah oo khatar ah.
Guud ahaan, Tert-Butylperoxy isopropyl carbonate wuxuu door muhiim ah ka ciyaaraa soo saarista agabyo kala duwan oo ku salaysan polymer waana qayb muhiim ah oo ka mid ah hababka wax soo saarka ee badeecooyin badan oo warshadeed.

Tert-Butyl peroxypivalate waa bilow wax ku ool ah oo loogu talagalay daaweynta kansarka
Soo saarista Polyethylene Cufnaan Yar (LDPE). Inta badan kiisaska, isku-darka peroxides kale ayaa loo isticmaalaa si loo hubiyo kala duwanaansho falcelin oo ballaaran. TBPV waxaa loo isticmaalaa sidii bilow u ah polymerization-ka joojinta ee vinyl chloride heerkulka u dhexeeya 50°C.
iyo 70°C.

Tert-Butyl peroxyneodecanoate waa isku-dhis organic peroxide ah oo si caadi ah loogu isticmaalo sidii bilow xagjir ah oo ku saabsan polymerization-ka monomers-ka kala duwan. Waxay si gaar ah ugu habboon tahay daaweynta resins polyester-ka aan dheregsanayn iyo resins vinyl ester, taasoo horseedaysa soo saarista agab isku dhafan, dahaadh, iyo dhejisyo. Intaa waxaa dheer, waxaa loo isticmaali karaa soo saarista balaastikada thermoset iyo elastomers. Tert-Butyl peroxyneodecanoate waxay heshaa codsiyada soo saarista alaabada ku salaysan polymer-ka halkaas oo loo baahan yahay bilowga polymerization-ka xagjirka ah. Waxaa loo yaqaanaa awooddeeda ay ku bilaabi karto hababka isku-xidhka iyo polymerization-ka, taasoo gacan ka geysanaysa sameynta agab polymer oo xooggan oo waara.

Tert-Butyl peroxyacetate waxaa loo isticmaali karaa bilaabista xalka (co) polymerization ee acrylates iyo methacrylates heerkulka u dhexeeya 100-170°C, iyo kuwo kale oo loogu talagalay soo saarista dahaarka.
Tert-Butyl peroxyacetate sidoo kale waxaa loo isticmaali karaa sidii bilowe loogu talagalay isku-darka iyo isku-darka polymerization-ka acrylates iyo methacrylates

TBPIN waa bilow wax ku ool ah oo loogu talagalay polymerization-ka ethylene-ka marka cadaadis sare la saaro hababka autoclave iyo tuber-ka labadaba. Si loo helo noocyo badan oo heerkul polymerization ah, isku-darka peroxides-ka kale ayaa lagu dabaqayaa ficil ahaan. Iyada oo ku xidhan xaaladaha falcelinta, TBPIN wuxuu firfircoon yahay heerkulka 210-240°C. TBPIN waxaa loo isticmaali karaa bilow ahaan xalka (co) polymerization-ka ee acrylates iyo methacrylates heerkulka 90-175°C, iyo kuwo kale oo loogu talagalay soo saarista dahaarka. TBPIN sidoo kale waxaa loo isticmaali karaa sidii
bilaabaha cufka iyo joojinta (co) polymerization ee acrylates iyo methacrylates heerkulka 90-130°C. TBPIN waxaa loo isticmaali karaa (co) polymerization ee styrene heerkulka 90-140°C.

Waxaa badanaa loo isticmaalaa sidii billowga polymerization-ka ee soo saarista polymers iyo balaastigyo kala duwan. Isku-dhafkan waxaa loo yaqaanaa awooddiisa uu ku bilaabo falgallada isku-xidhka iyo polymerization-ka, taasoo ka dhigaysa qayb muhiim ah oo ka mid ah soo saarista dhejisyada, dahaarka, iyo alaabada kale ee ku salaysan polymer-ka.
Tert-Amylperoxy 2-ethylhexyl carbonate ayaa sidoo kale loo isticmaalaa soo saarista resins-ka thermoset, kuwaas oo si weyn loogu isticmaalo warshadaha dhismaha, baabuurta, iyo hawada sare. Sifooyinka kiimikada ee ay leedahay ayaa ka dhigaya qayb qiimo leh oo ka mid ah abuurista agab waara oo u adkaysta kulaylka.
Intaa waxaa dheer, isku-darkan waxaa loo yaqaanaa xasilloonidiisa iyo isbeddel yar, taasoo ka dhigaysa doorasho ammaan ah oo wax ku ool ah oo loogu talagalay codsiyada warshadaha. Isticmaalkiisa waa la nidaamiyaa oo la xakameeyaa sababtoo ah falcelintiisa suurtagalka ah iyo dabeecadda khatarta ah, waana muhiim in la maareeyo oo la kaydiyo iyadoo la raacayo tallaabooyin badbaado oo habboon.
Guud ahaan, Tert-Amylperoxy 2-ethylhexyl carbonate wuxuu door muhiim ah ka ciyaaraa soo saarista agabyo kala duwan oo ku salaysan polymer waana qayb muhiim ah oo ka mid ah hababka wax soo saarka ee badeecooyin badan oo warshadeed.

Tert-Amyl peroxypivalate waa bilaabe (75% walax firfircoon)
isododecane) si loogu isticmaalo (isku-dubaridka) polymerization-ka ethylene, styrene, vinyl chloride, vinylidine chloride iyo polyols.
Polymerization of ethylene: Tert-Amyl peroxypivalate waa bilow wax ku ool ah oo loogu talagalay polymerization ethylene marka cadaadis sare la saaro hababka autoclave iyo tube labadaba.
Si loo helo heerkul ballaaran oo polymerization ah, isku-darka peroxides kale ayaa lagu dabaqayaa ficil ahaan.
Polymerization of vinyl chloride: Tert-Amyl peroxypivalate waxaa loo isticmaali karaa sidii bilow u ah polymerization of vinyl chloride ee heerkulka u dhexeeya 50°C iyo 65°C. Tert-Amyl peroxypivalate waxaa loo isticmaali karaa iyadoo lala kaashanayo bilaabayaasha kale si loo kordhiyo waxtarka falgalka

Tert-Amyl peroxy-2-ethylhexanoate waxaa loo isticmaali karaa in lagu bilaabo isku-darka (co) polymerization ee acrylates iyo methacrylates heerkulka u dhexeeya 70°C iyo 120°C.
Tert-Amyl peroxy-2-ethylhexanoate waxaa lagu dabaqi karaa suspension iyo sidoo kale solvent iyo bulk polymerization. Tert-Amyl peroxy-2-ethylhexanoate waxaa sidoo kale loo isticmaali karaa copolymerization ee styrene iyo acrylonitrile iyo copolymers-ka ku salaysan vinyl acetate.

EHP waa bilowe (75% firfircoon)
maaddada) ee loogu talagalay (co) polymerization ee ethylene, vinyl
koloriin iyo vinylidene chloride.

BPO32% waxaa loo isticmaali karaa sidii walax bur ah. Waxa kale oo loo isticmaali karaa calaamadaynta waddada.

BPO27% waxaa loo isticmaali karaa sidii walax bur ah. Waxa kale oo loo isticmaali karaa calaamadaynta waddada.

TMCH waa bilowe (90% walax firfircoon oo ku jirta isododecane) oo loogu talagalay (co) polymerization-ka ethylene, styrene, acrylonitrile, (meth)acrylates iyo monomers-ka ku salaysan diethylene glycol bis (allyl carbonate).

CH80 waa bilaabaha (co) polymerization ee acrylates iyo methacrylates.

DTAC waxaa loo isticmaali karaa bilow u ah polymerization-ka styrene. DTAC waa peroxide aan shaqaynayn. Xaaladaha falgalka ee u dhigma, waqtiyada polymerization-ka waxaa la dhimi karaa ilaa 10% marka la barbar dhigo kuwa ay soo saaraan monofunctional peroxides oo leh isla dhaqdhaqaaqaas.
Trigonox® 122-C80 si guul leh ayaa loogu isticmaali karaa sidii bilow u ah (co) polymerization-ka ethylene ee cufnaanta hoose. Trigonox® 122-C80 waxaa sidoo kale loo isticmaali karaa bilow u ah (co) polymerization-ka acrylonitrile, acrylates iyo methacrylates.